Precise Cross-Coupling Control during Oxidative Coupling Polymerization

Miniplant-Scale Analysis of Oxidative Coupling of Methane Process

For more than three decades, Oxidative Coupling of Methane (OCM) process has been comprehensively investigated as an attractive alternative for the commercially available ethylene production technologies such as ethane and naphtha cracking. Developing a suitable catalyst and proper reactor feeding policy, reviewing and deploying the efficient methods in the separation and purification of the un...

Metal-free oxidative cross-coupling of diazirines with arylboronic acids.

We report herein a metal-free cross-coupling of diazirines with arylboronic acids under oxidative conditions. The reaction affords a series of substituted olefins. It is proposed that the interaction between the nitrogen on diazirine with arylboronic acid plays a key role in this transformation.

Metal-free oxidative para cross-coupling of phenols.

Recent Progress in Decarboxylative Oxidative Cross‐Coupling for Biaryl Synthesis

The beginning of the 21st century has seen tremendous growth in the field of decarboxylative activation. Benzoic acid derivatives are now recognised as atom-economic alternatives to traditional cross-coupling partners, and they also benefit from being inexpensive, readily available and shelf-stable reagents. In this microreview we discuss recent developments in the coupling of benzoic acid deri...

Elements of regiocontrol in palladium-catalyzed oxidative arene cross-coupling.

An increasing emphasis on waste minimization has prompted research aimed at replacing common synthetic techniques with greener alternatives. In biaryl synthesis, direct arylation1,2 is an emerging alternative to Suzuki and Stille couplings;3 however, a more efficient strategy would involve the direct catalytic crosscoupling of two arenes without recourse to stoichiometric activating groups (eq ...